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Rubber compositions, crosslinkable rubber compositions and oil seals and rubber hoses made therefrom

机译:橡胶组合物,可交联的橡胶组合物以及由其制成的油封和橡胶软管

摘要

PURPOSE:To obtain a rubber compsn. having excellent roll processability, mechanical strengths, etc., by reacting a specified rubber-forming polymer, polyorganohydrogensiloxane and a transition-metal compd. while shearing deformation is applied. CONSTITUTION:A rubber-forming polymer (A) is obtd. by compounding 3-70wt.% polyorganosiloxane of the formula (wherein R is a (substd.) monovalent org. group and 0.02-10mol.% of R is vinyl group; a is 1.900-2.004) (i) and 97-30wt.% org. rubber whose Mooney viscosity at 100 deg.C is 10-200 (e.g., acrylic rubber) (ii). 100pts.wt. component A, 0.005-50pts.wt. polyorganohydrogensiloxane (B) having 2 or more H-Si bonds in the molecule and 0.00001-1pt.wt. transition-metal compd. (C) of group VIII of the periodic table, pref. a platinum compd., are compounded and hydrosilylation thereof is done while shearing deformation is applied thereto.
机译:目的:获得橡胶复合物。通过使指定的形成橡胶的聚合物,聚有机氢硅氧烷和过渡金属化合物反应,具有优异的辊加工性能,机械强度等。同时施加剪切变形。组成:形成橡胶的聚合物(A)。通过将3-70wt。%的下式的聚有机硅氧烷进行配混(其中R是(≤)一价的有机基团,R 0.02-10mol。%是乙烯基; a是1.900-2.004)(i)和97-30wt。%。 %org。在100℃时门尼粘度为10-200的橡胶(例如丙烯酸橡胶)(ii)。 100pts.wt。组分A,0.005-50pts.wt。在分子中具有2个或更多个H-Si键和0.00001-1pt.wt的聚有机氢硅氧烷(B)。过渡金属化合物(C)周期表第VIII族,优选。混合铂化合物,并在对其施加剪切变形的同时进行其氢化硅烷化。

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