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RECOVERY OF URANIUM FROM WET PROCESS PHOSPHORIC ACID BY LIQUID-SOLID ION EXCHANGE

机译:液固离子交换从湿法磷酸中回收铀

摘要

Recovery of uranium from crude wet process phosphoric acid (WPA) by cation exchange using as cation exchanger a resin comprising active amino phosphonic or hydroxy phosphonic groups linked to a matrix. The operational steps comprise reduction of uranium in the WPA to the tetravalent state, contacting the WPA with the cation exchange resin to load the latter with tetravalent uranium, displacing Fe+2 from the resin, washing the resin with aqueous ammonia, eluting the resin with a carbonate-bicarbonate solution and precipitating uranium from the eluate.
机译:使用包含与基质连接的活性氨基膦酸或羟基膦酸基团的树脂作为阳离子交换剂,通过阳离子交换从粗湿法磷酸(WPA)中回收铀。操作步骤包括将WPA中的铀还原为四价态,使WPA与阳离子交换树脂接触,以将四价铀加载到阳离子交换树脂中,从树脂中置换Fe + 2,用氨水洗涤树脂,然后用碳酸盐-碳酸氢盐溶液并从洗脱液中沉淀出铀。

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