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SUBSTITUTED PHENYLUREA DERIVATIVE AND HERBICIDE CONTAINING SAID DERIVATIVE AS ACTIVE COMPONENT
SUBSTITUTED PHENYLUREA DERIVATIVE AND HERBICIDE CONTAINING SAID DERIVATIVE AS ACTIVE COMPONENT
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机译:取代的苯脲衍生物和称谓衍生物的除草剂为活性成分
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摘要
NEW MATERIAL:The N'-phenyl-N-methylurea derivative of formula I (A is alkylene; R1 is methyl or methoxy; R2 is H or methyl). EXAMPLE:1-[4-(2,3-Dihydro-2-methyl-5-benzofuranylmethyloxy)pheny-l]-3- methoxy-3-methylurea. USE:A herbicide. PREPARATION:The objective compound can be produced e.g. by reacting a compound of formula II [e.g. 4-(2,4-dihydro-2-methyl-5-benzofuranylmethyloxy) aniline] with a compound of formula III (Z is halogen) (e.g. N-methoxy-N- methylcarbamoyl chloride) optionally in a solvent (e.g. acetone) in the presence of a base (e.g. pyridine) at 0-150 deg.C.
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机译:新材料:式I的N′-苯基-N-甲基脲衍生物(A为亚烷基; R 1为甲基或甲氧基; R 2为H或甲基)。实施例:1- [4-(2,3-二氢-2-甲基-5-苯并呋喃基甲氧基)苯基-1] -3-甲氧基-3-甲基脲。用途:除草剂。制备:可以例如制备目标化合物。通过使式II化合物[例如通过4-(2,4-二氢-2-甲基-5-苯并呋喃基甲氧基)苯胺]与式Ⅲ化合物(Z为卤素)(例如N-甲氧基-N-甲基氨基甲酰氯),任选在溶剂(例如丙酮)中在0-150℃存在碱(例如吡啶)。
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