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UREA DERIVATIVE AND SELECTIVE HERBICIDE CONTAINING SAID DERIVATIVE AS ACTIVE COMPONENT

机译:含有所说的衍生物的尿素衍生物和选择性除草剂作为活性成分

摘要

NEW MATERIAL:The 1,3-dibenzylurea derivative of formula I (X and Y are H, halogen, lower alkyl or lower alkoxy; R1 is methyl or ethyl; R2 and R3 are H, lower or alkyl; R4 and R5 are H, methyl or ethyl; m and n are 1 or 2; at least one of R2 and R3 is H, and R4 and R5 are not methyl at the same time). EXAMPLE:3-(2-Methyl-alpha-ethyl-alpha-methylbenzyl)-1-(alpha-ethyl-alp ha-methyl-benzyl)urea. USE:Selective herbicide having excellent activity especially against cyperaceous weeds. PROCESS:The compound of formula I can be prepared by the thermal reaction of the isocyanate of formula II with the amine of formula III in a solvent such as benzene, tetrahydrofuran, etc. at room temperature -50 deg.C for 1-8hr.
机译:新材料:式I的1,3-二苄基脲衍生物(X和Y为H,卤素,低级烷基或低级烷氧基; R 1为甲基或乙基; R 2和R 3为H,低级或烷基; R 4和R 5为H,甲基或乙基; m和n为1或2; R 2和R 3的至少一个为H,且R 4和R <5>不能同时是甲基。实施例:3-(2-甲基-α-乙基-α-甲基苄基)-1-(α-乙基-α-卤代甲基-苄基)脲。用途:选择性除草剂,具有优异的活性,尤其是对莎草科杂草。过程:可以通过在溶剂如苯,四氢呋喃等中在室温-50℃下使式II的异氰酸酯与式III的胺热反应制备式I的化合物1-8小时。

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