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Crystalline galloaluminosilicates, steam-modified crystalline galloaluminosilicates, their preparation and their use as catalysts and catalyst supports
Crystalline galloaluminosilicates, steam-modified crystalline galloaluminosilicates, their preparation and their use as catalysts and catalyst supports
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机译:结晶镓铝硅酸盐,蒸汽改性的结晶镓铝硅酸盐,其制备方法及其在催化剂和催化剂载体中的用途
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摘要
The invention relates to crystalline galloaluminosilicates having an X-ray diffraction pattern substantially the same as that of an MFI-zeolite and a composition in terms of mole ratios of oxides as follows: 0.9+/-0.2 M2/nO.Al2O3. a Ga2O3. b SiO2.zH2O wherein M is a cation, n is the valence of the cation, a has a value between 0.0001 and 2, b has a value of at least 12 and z has a value of from 0 to 40. Ion-exchanged forms, calcined forms and steam-treated forms of the crystalline galloaluminosilicates are also described. Such materials can be used as catalysts and catalyst supports. The steam-treated form is particularly useful as a catalyst for the production of aromatic hydrocarbons from C2 to C12 hydrocarbon feedstocks.
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机译:本发明涉及具有与MFI-沸石基本上相同的X-射线衍射图并且其氧化物的摩尔比为0.9 +/- 0.2M 2 /nO.Al 2 O 3的结晶镓铝硅酸盐。 Ga 2 O 3。 b SiO2.zH2O,其中M为阳离子,n为阳离子的化合价,a的值为0.0001至2,b的值至少为12,z的值为0至40。离子交换形式还描述了结晶镓铝硅酸盐的煅烧形式和蒸汽处理形式。这样的材料可以用作催化剂和催化剂载体。蒸汽处理的形式特别用作从C 2至C 12烃原料生产芳族烃的催化剂。
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