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Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups and synthetic resin compositions

机译:具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸酯以及合成树脂组合物

摘要

Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula:wherein:R, is alkyl having from one to about twelve carbon atoms;R2, R3 and R4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting ofwherein:R5 is selected from the group consisting of hydrogen oxyl O, alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms: 2,3-epoxypropyl, acyl having from one to about eight carbon atoms andin which Rs is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y, is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; andZ, is selected from the group consisting of -CH andwherein R7 is alkyl having from one to about twelve carbon atoms: andwherein:R6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl; andZ2 is selected from the group consisting of C=O; -CH-O-Y2;in which R7 is alkyl having from one to about twelve carbon atoms; R8 is alkylene having from one to about eight carbon atoms and Y2 is selected from the group consisting of hydrogen and acyl having from one to about eight carbon atoms.
机译:提供具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸盐,其化学式为:其中: R,是具有1至约12个碳原子的烷基; R 2 ,R 3 和R 4 分别选自氢和具有1至约十二个碳原子的烷基; m为0或1; n为0或1; X从包含以下内容的组中选择<化学ID =“ chema02” />其中: R 5 选自由氢氧基O,具有1至约十二个碳原子的烷基组成的组;具有七个至约十八个碳原子的芳基烷基:EPO ->原子:2,3-环氧丙基,具有一个至约八个碳原子的酰基和<化学ID =” chema03” />,其中R s 选自氢,具有1至约十二个碳原子的烷基和苯基以及Y,选自以下组成的组:氢具有1至约十二个碳原子的酰基;和 Z是从-CH和其中R 7 是具有1至约12个碳原子的烷基:<化学ID =“ chema06” />其中 R 6 选自氢,具有1至约12个碳原子的烷基和苯基; Z 2 选自> C = O; -CH-O-Y 2 ;<化学ID =“ chema07” />,其中R 7 是具有1至约十二个碳原子的烷基; R 8 是具有1至约8个碳原子的亚烷基,Y 2 选自氢和具有1至约8个碳原子的酰基。 ListItem>

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