首页> 外国专利> Polyester polyols based on 2-methyl pentane diol-1,5, 2-ethyl butane diol-1,4, 2-methyl glutaric acid and/or 2-ethyl succinic acid, liquid at room temperature, and the resultant dicarbonic-acid derivatives, process for their preparation and their use in the preparation of synthetics by the polyisocyanate polyaddition process

Polyester polyols based on 2-methyl pentane diol-1,5, 2-ethyl butane diol-1,4, 2-methyl glutaric acid and/or 2-ethyl succinic acid, liquid at room temperature, and the resultant dicarbonic-acid derivatives, process for their preparation and their use in the preparation of synthetics by the polyisocyanate polyaddition process

机译:基于2-甲基戊二醇-1,5、2-乙基丁二醇-1,4、2-甲基戊二酸和/或2-乙基琥珀酸的聚酯多元醇,在室温下为液体,以及所得的二碳酸衍生物,其制备方法及其在通过多异氰酸酯加成法制备合成物中的用途

摘要

The invention describes liquid polyester polyols having an average functionality of from 2 to 3, a hydroxyl number of 25 to 400, an acid number of less than 10 and a viscosity at 25 ° C of 200 to 10⁵m.Pa.s at 25 ° C, the units having at least one of the structures -O-CH₂-CH (CH₃) -CH₂-CH₂-CH₂-O- -O-CH₂-CH (C₂H₅) -CH₂-CH₂-O-, -O-CH (CH₃) -CH₂-CH₂-CO- or -OC-CH (C₂H₅) -CH₂-CO- bonded form.; The polyester polyols can be 2-Ethylbutandiol-1,4, 2-methylglutaric acid and / or 2-ethylsuccinic acid or derivatives thereof are prepared by polycondensation or transesterification of 2-methyl pentanediol-1,5, optionally with the concomitant use of other organic acids and polyhydric Polycarbon aliphatic alcohols.; The polyester polyols according to the invention are suitable for the production of compact or cellular polyurethane or polyurethane material Polyharn plastics, preferably polyurethane elastomers, after the poly isocyanate polyaddition process.
机译:本发明描述了液体聚酯多元醇,其平均官能度为2-3,羟值为25-400,酸值为小于10,并且在25℃下的粘度在25℃下为200-10μm.Pa.s。 ,具有至少一种结构的单元-O-CH 2 -CH(CH 3)-CH 2 -CH 2 -CH 2 -O- -O-CH 2 -CH(C 2 H 4)-CH 2 -CH 2 -O-,-O-CH( CH 3)-CH 2 -CH 2 -CO-或-OC-CH(C 2 H 4)-CH 2 -CO-键合形式。聚酯多元醇可以是2-乙基丁二醇-1,4、2-甲基戊二酸和/或2-乙基琥珀酸或其衍生物,其通过2-甲基戊二醇-1,5的缩聚或酯交换反应制备,任选地与其他有机酸和多元聚碳酸酯脂族醇。根据本发明的聚酯多元醇适用于在聚异氰酸酯加聚方法之后生产致密的或多孔的聚氨酯或聚氨酯材料的Polyharn塑料,优选聚氨酯弹性体。

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