Isomers of raw feed streams comprising paraffinic and cyclic hydrocarbons and double functional processes for ring opening

摘要

A C4-C6 feed containing low octane paraffins and substantial amounts of cyclic hydrocarbons in contacted with hydrogen and a high chloride, platinum alumina catalyst under conditions selected simultaneously to open cyclic hydrocarbon rings and isomerize paraffins to more highly branched paraffins in order to produce a high octane product stream which has a relatively low cyclic content. The process is operated at relatively low severity conditions that provide favourable equilibrium conditions for isoparaffin conversion, comprising a temperature of 40 to 260 DEG C (105 to 500 DEG F), a pressure of 7 to 70 barsg (0.8 to 7.1 MPa) and a space velocity of 0.5 to 12 hr-1, while maintaining a chloride concentration in the feed stream of 30 to 300 wt ppm. The ring opening is also obtained without excessive generation of light hydrocarbons. Multiple stage reaction zones may be used to operate the first stage at slightly higher severity (higher temperature) than the second stage to maximize ring opening and obtain favourable equilibrium of iso- to normal -paraffins.