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New vinyl monomers capable of forming side-chain liquid crystalline polymers and the resulting polymers
New vinyl monomers capable of forming side-chain liquid crystalline polymers and the resulting polymers
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机译:能够形成侧链液晶聚合物的新型乙烯基单体及所得聚合物
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摘要
There is disclosed a new vinyl monomer capable of forming polymeric vesicles, micelles, monolayers, and side-chain liquid crystalline polymers. The vinyl monomer is of the formula ##STR1## wherein R.sub.1 is substituted or unsubstituted long chain alkyl or aryl and R.sub.2 is a hydrogen atom, alkyl, or aryl.PPThe side- chain liquid crystalline polymers can be formed by free radical polymerization or by anionic polymerizations techniques. The different reaction methods give polymers of different configuration; the anionic technique results in a polymer having a nitrogen atom in the backbone. The polymers are useful in film and fiber formation and display good toughness.
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