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Process for producing stretched molded articles of conjugated polymers and highly conductive compositions of said polymers

机译:制备共轭聚合物的拉伸模塑制品的方法以及所述聚合物的高导电性组合物

摘要

A process for producing a stretched molded article of a conjugated polymer,hich comprises subjecting a polymer precursor having a repeating unit represented by the general formula (I) ##STR1## (wherein R. sub.1 is a group which forms a C--C conjugated system together with a vinylene group which is formed upon the dehydrogenation of the CH-- Ch.sub.2 -- group; and R.sub.2 is a group which is to be eliminated from the alpha- position carbon of the CH--CH.sub.2 -- group simultaneously with the elimination of one of the hydrogen atoms bonding to the beta-position carbon of the CH--Ch.sub.2 -- group) to stretching in the swelling state and then subjecting the stretched precursor polymer to elimination of the R.sub.2 group, and a conductive composition of the stretched molded article of the conjugated polymer, comprising the comjugated polymer and a dopant as essential components.
机译:一种制备共轭聚合物的拉伸模塑制品的方法,该方法包括使具有由通式(I)表示的重复单元的聚合物前体进行处理(其中R.sub.1是形成C的基团)。 -C共轭体系以及在> CH- Ch.sub.2-基团脱氢时形成的亚乙烯基; R 2是要从α-位除去的基团CH-CH.sub.2-基团的碳原子同时消除与CH-Ch.sub.2-基团的β位碳键合的氢原子之一)使其处于溶胀状态,然后使拉伸的前体聚合物消除R 2基团,以及共轭聚合物的拉伸模塑制品的导电组合物,其包含共轭聚合物和掺杂剂作为基本成分。

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