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ORGANOPOLYSILOXANE COPOLYMER, ITS PREPARATION, METHOD FOR REMOVING DISSOLVED METAL FROM AQUEOUS OR ORGANIC SOLUTION, AND METHOD FOR ADSORPTION OF GASEOUS ORGANIC COMPOUND
ORGANOPOLYSILOXANE COPOLYMER, ITS PREPARATION, METHOD FOR REMOVING DISSOLVED METAL FROM AQUEOUS OR ORGANIC SOLUTION, AND METHOD FOR ADSORPTION OF GASEOUS ORGANIC COMPOUND
The invention relates to organosiloxane-amine copolycondensates as random or block copolycondensates or mixtures thereof of …IMAGE… and X - R4 (II). …??R1 to R4 is …IMAGE…. …??R5 is directly bonded to the nitrogen atom or the single-bonded radical X and is an alkylene group, cycloalkylene group or …IMAGE… or …IMAGE…. …??In these formulae, n is 1 to 6 and m is 0 to 6. The free valences of the oxygen atoms bonded to the silicon atom are saturated by silicon atoms of other groups of the formula (III), if appropriate with the incorporation of cross-linkers. X stands for -NH2, -NH-(CH2)2-NH2, -NH-(CH2)2-NH-(CH2)2-NH2, -Cl,-Br,-I,-SH,-P(C6H5)2, …IMAGE… where R" is H or an alkyl group. Preparation processes and the use of the process products for the removal of dissolved metals from solutions or for the adsorption of organic solvents are also given.
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机译:本发明涉及有机硅氧烷-胺共缩聚物,其为……和X-R 4(II)的无规或嵌段共缩聚物或它们的混合物。 …?> R <1>至R <4>为…...。 … R 5与氮原子或单键基团X直接键合,为亚烷基,亚环烷基或……或……。在这些式中,n为1至6且m为0至6。键合到硅原子上的氧原子的自由价被式(III)的其他基团的硅原子饱和。与交联剂的结合。 X代表-NH2,-NH-(CH2)2-NH2,-NH-(CH2)2-NH-(CH2)2-NH2,-Cl,-Br,-I,-SH,-P(C6H5) 2,…<图像>…,其中R”是H或烷基。还提供了制备方法和该方法产物用于从溶液中除去溶解的金属或用于吸附有机溶剂的方法。
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