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4,4'-DIMERCAPTODIPHENYL SULFIDE DIMETHACRYLATE

机译:4,4'-二巯基二苯硫醚二甲基丙烯酸酯

摘要

NEW MATERIAL:A compound shown by the formula. USE:A polymerizable monomer producing a transparent cured material having high heat resistance, low water absorption properties and high refractive index. A raw material for coating compound, adhesive, casting material, photosensitive resin, optical material, etc. PREPARATION:4,4'-Dimercaptodiphenyl sulfide is converted into an alkali metallic salt by using an aqueous solution of NaOH, the solution is mixed with a phase transfer catalyst (e.g. tetraethylammonium bromide), an alkali and approximately the same volume ratio of a water-insoluble organic solvent (e.g. benzene) stable to acid as that of the aqueous solution of the alkali and a methacrylic acid halide is gradually dripped into the reaction solution of two phase system to give a compound shown by the formula.
机译:新材料:分子式所示的化合物。用途:一种可聚合的单体,可生产具有高耐热性,低吸水性和高折射率的透明固化材料。涂料的原料,粘合剂,铸造材料,光敏树脂,光学材料等。制备:4,4'-二巯基二苯硫醚通过使用NaOH水溶液转化为碱金属盐,将该溶液与将相转移催化剂(例如四乙基溴化铵),碱和对酸稳定的水不溶性有机溶剂(例如苯)的体积比与碱和甲基丙烯酸卤化物的溶液逐渐滴加到该溶液中。两相体系的反应溶液,得到下式所示的化合物。

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