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Chiral esters of mesogenic-carboxylic acids, process for their preparation and their use as doping agents in liquid crystal phases

机译:介晶羧酸的手性酯,其制备方法及其在液晶相中作为掺杂剂的用途

摘要

1. An ester of a chiral alcohol and a mesogenic carboxylic acid, which is of the general formula (I) see diagramm : EP0217240,P6,F2 in which the symbols have the following meanings : n denotes 0 or 1, R**1 denotes a straight-chain or branched (C1 -C4 )alkyl which is substituted by halogen, in particular fluorine, R**2 denotes unsubstituted or substituted (C6 -C18 ) aryl, cyclo (C5 -C12 )alkyl or mononuclear or binuclear heteroaryl possessing a five-membered and/or sixmembered ring, and MC denotes R**3 -(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 0 or denotes OC-(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 1, R**3 denotes a straight-chain (C4 -C10 )alkyl in which a CH2 group can be replaced by an 0 atom, A**1 , A**2 independently of one another denote unsubstituted 1,4-phenylene or 1-4-cyclohexylene, B denotes CO-0 or 0-CO, n1 denotes 1 n2 denotes 0 or 1 and n3 denotes 1 or 2.
机译:1.通式(I)的手性醇和介晶羧酸的酯,见图:EP0217240,P6,F2,其中的符号具有以下含义:n表示0或1,R ** 1表示被卤素,特别是氟取代的直链或支链(C1-C4)烷基,R ** 2表示未取代或取代的(C6-C18)芳基,环(C5-C12)烷基或单核或双核杂芳基拥有一个五元和/或六元环,MC表示R ** 3--(A ** 1--)n1(B-)n2(A ** 2--)n3 CO其中n = 0或表示OC-( A ** 1-)n1(B-)n2(A ** 2-)n3 CO其中n = 1,R ** 3表示其中CH2可被取代的直链(C4-C10)烷基0原子,A ** 1,A ** 2彼此独立地表示未取代的1,4-亚苯基或1-4-亚环己基; B表示CO-0或0-CO,n1表示1 n2表示0或1; n3表示1或2。

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