首页> 外国专利> STYRENE DERIVATIVE, POLYSTYRENE DERIVATIVE COMPRISING THE SAME, PROCESS FOR PREPARING SAID POLYSTYRENE DERIVATIVE, AND ULTRAVIOLET ABSORBER COMPRISING SAID STYRENE DERIVATIVE OR POLYSTYRENE DERIVATIVE.

STYRENE DERIVATIVE, POLYSTYRENE DERIVATIVE COMPRISING THE SAME, PROCESS FOR PREPARING SAID POLYSTYRENE DERIVATIVE, AND ULTRAVIOLET ABSORBER COMPRISING SAID STYRENE DERIVATIVE OR POLYSTYRENE DERIVATIVE.

机译:苯乙烯衍生物,包括相同的聚苯乙烯衍生物,制备所述的聚苯乙烯衍生物的方法,以及包含所述的苯乙烯衍生物或聚苯乙烯衍生物的紫外吸收剂。

摘要

The styrene derivative of the present invention is characterized by comprising a compound represented by general formula (I), wherein at least one of R1, Rz, Ra, R4 and R5 is a carboxyl group, an alkyl group having 1 to 5 carbon atoms, a hydroxyalkyl group having 1 to 5 carbon atoms, a carboxyalkyl group having 2 to 6 carbon atoms, an alkoxycarbonyl group having 2 to 6 carbon atoms, an alkoxycarbonylalkyl group having 2 to 6 carbon atoms, or an aryl group and the remainders are each a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R6 is a sulfur atom or an oxygen atom. The styrene derivative has excellent capability of absorbing an ultraviolet ray having a wavelength form 290 nm, i.e., the shortest wavelength contained in sunrays reaching the surface of the earth, to 360 nm having an effect of causing the change In the plastics. The polystyrene derivative of the present invention is characterized by maintaining high water solubility through polymerization of said styrene derivative and causing no skin absorption, i.e., having high safety to the human body. Since the ultraviolet absorption wavelength region is the same as that which brings about a sunburn of the skin, which renders the polystyrene derivative suitable for use as an ultraviolet absorber. Further, according to the process for preparing the polystyrene derivative of the present invention, the polystyrene derivative can be purified in the stage of a monomer, which makes it possible to provide a polystyrene derivative having high quality and high stability.
机译:本发明的苯乙烯衍生物的特征在于包含通式(I)表示的化合物,其中R 1 ,Rz,Ra,R 4 和R 5 是羧基,具有1至5个碳原子的烷基,具有1至5个碳原子的羟烷基,具有2至6个碳原子的羧烷基,具有2至5个碳原子的烷氧基羰基。 6个碳原子,具有2至6个碳原子的烷氧基羰基烷基或芳基,其余分别为氢原子或具有1至5个碳原子的烷基,且R Sub 6 为硫原子或氧原子。苯乙烯衍生物具有优异的吸收能力,该吸收剂具有290nm的波长形式的紫外线,即到达地球表面的阳光中所含的最短波长,为360nm,具有引起塑料变化的效果。本发明的聚苯乙烯衍生物的特征在于通过所述苯乙烯衍生物的聚合来保持高水溶性,并且不引起皮肤吸收,即对人体具有高安全性。由于紫外线吸收波长区域与引起皮肤晒伤的波长区域相同,因此使得聚苯乙烯衍生物适合用作紫外线吸收剂。此外,根据本发明的聚苯乙烯衍生物的制备方法,可以在单体阶段纯化聚苯乙烯衍生物,这使得可以提供具有高质量和高稳定性的聚苯乙烯衍生物。

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