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A process to produce O-silyl O,N-ketene acetals
A process to produce O-silyl O,N-ketene acetals
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机译:一种生产O-甲硅烷基O,N-乙烯酮缩醛的方法
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摘要
A process for preparing O-silyl O,N-ketene acetals having the formula,R₂C=C(OSiRnX3-n)(NRa₂) or The process comprises contacting an alpha-haloamide with an alkali metal in the presence of an excess of an organohalosilane, the alpha-haloamide having the formula, the organohalosilane having the formula,RnSiX4-n ;and facilitating reaction among the alpha-haloamide, the alkali metal and the organohalosilane to form the O-silyl O,N-ketene acetal and alkali metal halides.
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机译:具有下式的O-甲硅烷基O,N-乙烯酮缩醛的制备方法:R 2 C = C(OSiR n Sub> X 3-n Sub>)(NR a Sup> 2)或 <图像文件=“ IMGA0001.GIF” he =“ 12” id =“ ia01” imgContent =“ chem” imgFormat =“ GIF” wi =“ 77” /> Chemistry>包括在过量的有机卤代硅烷存在下使α-卤代酰胺与碱金属接触,所述α-卤代酰胺具有下式: <图像文件=“ IMGA0002.GIF” he =“ 47” id =“ ia02” imgContent =“ chem” imgFormat =“ GIF” wi =“ 52” /> Chemistry>有机卤硅烷有公式,R n Sub> SiX 4-n Sub>;促进α-卤代酰胺,碱金属和有机卤代硅烷之间的反应,形成O-甲硅烷基O,N-烯酮缩醛和碱金属卤化物。
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