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MORDENITE-CONTAINING CATALYST, ITS PREPARATION AND ITS USE IN THE ISOMERISATION OF FRACTIONS RICH IN NORMAL PARAFFINS

机译:含丝光沸石的催化剂,其制备及其在正构石蜡中富集馏分的异构化中的用途

摘要

1. A catalyst containing by weight : a) from 10 to 99.99% of a mordenite adsorbing molecules of a kinetic diameter larger than about 6.6x10**-10 m, having a Si/Al atomic ratio from about 5 to 50, a sodium content by weight lower than 0.2% of the total weight of dry mordenite, a volume V of elementary mesh from 2.73 to 2.78 cubic nanometers, a benzene adsorption capacity of more than 5% by weight with respect to the dry mordenite weight, said mordenite being in major part shaped as needles, b) from 0 to 89.99% of a matrix selected from the group consisting of alumina, silica, magnesia, zirconia, natural clays or mixtures thereof, c) from 0.005 to 15% of at least one metal from group VIII of the periodic classification of elements, and d) from 0.005 to 10% of at least one metal group IVA of the periodic classification, selected from the group consisting of tin, germanium and lead.
机译:1.一种催化剂,其按重量计包含:a)动力学直径大于约6.6x10 **-10 m的丝光沸石吸附分子的10至99.99%,其Si / Al原子比为约5至50,钠重量含量低于干丝光沸石总重量的0.2%,基本筛网的体积V为2.73至2.78立方纳米,相对于干丝光沸石重量,苯吸附能力大于5%(重量),所说的丝光沸石为在主要形状为针状的部件中,b)选自氧化铝,二氧化硅,氧化镁,氧化锆,天然粘土或它们的混合物的基质的0至89.99%,c)0.005至15%的至少一种金属元素的周期性分类的第VIII族,和d)选自锡,锗和铅的至少一种周期性分类的金属IVA的0.005-10%。

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