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GAMMA-PYRONE-3-CARBOXAMIDE DERIVATIVE, ITS PRODUCTION AND PLANT GROWTH RETARDANT
GAMMA-PYRONE-3-CARBOXAMIDE DERIVATIVE, ITS PRODUCTION AND PLANT GROWTH RETARDANT
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机译:GAMMA-PYRONE-3-羧酰胺衍生物,其生产和植物生长延缓剂
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NEW MATERIAL:A gamma-pyrone-3-carboxamide derivative expressed by formula I [R1 and R2 are 1-11C alkyl, lower alkenyl, lower alkynyl or phenyl which may be substituted; R3 is H, halogen, lower alkyl, lower alkenyl, lower alkynyl or phenyl which may be substituted; or R2 and R3 together represent (CH2)m ((m) is 3 or 4); R4 and R5 may be same or different and each are H or lower alkyl; R6 is phenyl which may be substituted]. EXAMPLE:5-Allyl-2,6-dimethyl-N-(2-methyl-1-phenyl-1-propenyl)-4-oxo-4H -pyran- carboxamide. USE:Useful as a plant growth retardant. PREPARATION:For example, a compound expressed by formula II (R7 is alkyl) is reacted with a compound expressed by formula III (R8 is alkyl, etc.) in the presence of molecular sieves to afford the compound expressed by formula I.
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机译:新材料:由式I表示的γ-吡喃酮-3-甲酰胺衍生物[R 1和R 2]为可以被取代的1-11C烷基,低级烯基,低级炔基或苯基; R 3为H,卤素,低级烷基,低级烯基,低级炔基或可被取代的苯基; R 2和R 3一起表示(CH 2)m((m)为3或4);或R 4和R 5可以相同或不同,分别为H或低级烷基。 R 6为可被取代的苯基]。实施例:5-烯丙基-2,6-二甲基-N-(2-甲基-1-苯基-1-丙烯基)-4-氧代-4H-吡喃甲酰胺。用途:用作植物生长抑制剂。制备:例如,在分子筛的存在下,使式II表示的化合物(R 7为烷基)与式III表示的化合物(R 8为烷基等)反应,得到式II的化合物。根据公式一
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