首页> 外国专利> Indan - 1,3 Dione derivative, herbicide composition, a method for controlling the growth indesejavel weeds and process to produce a derivative of indan - 1,3 Dione

Indan - 1,3 Dione derivative, herbicide composition, a method for controlling the growth indesejavel weeds and process to produce a derivative of indan - 1,3 Dione

机译:茚满-1,3二酮衍生物,除草剂组合物,控制靛蓝杂草生长的方法和生产茚满-1,3二酮衍生物的方法

摘要

The present invention provides an indan-1,3-dione derivative represented by the following formula (I): CHEM wherein R1 represents a hydrogen atom or a lower alkyl group; R2 represents a group represented by CHEM wherein E represents a (substituted) phenyl group or a (substituted) pyridyl group; Y represents a hydroxyl group; and Z represents a halogen atom, a (substituted) alkylsulfonyloxy group or a (substituted) phenylsulfonyloxy group, or Y and Z are bonded to represent -O-; and A represents a (substituted) 1,3-butadienylene group or a (substituted) 1,3-azabutadienylene group, and a herbicidal composition containing the same as an active ingredient. The present invention further provides an indan-1,3-dione derivative represented by the following formula (II): CHEM wherein R1 and A represent the same meanings as above and R3 represents a group represented by CHEM wherein E represents the same meanings as above; and W1 and W2 each represents hydroxyl group or form a carbon-carbon bond by combining with each other, which is available as a synthetic intermediate for the compound of the formula (I). The compound of the formula (I) shows high herbicidal activity against gramineous weeds, cyperaceous weeds, etc. but shows markedly low phytotoxicity against crops.
机译:本发明提供由下式(I)表示的茚满-1,3-二酮衍生物:其中R 1表示氢原子或低级烷基的& CHEM&。 R 2表示表示的基团,其中,E表示(取代的)苯基或(取代的)吡啶基。 Y代表羟基; Z表示卤素原子,(取代的)烷基磺酰氧基或(取代的)苯基磺酰氧基,或Y和Z键合表示-O-。 A表示(取代的)1,3-丁二烯基或(取代的)1,3-氮杂丁二烯基,以及含有其作为有效成分的除草组合物。本发明进一步提供由下式(II)表示的茚满-1,3-二酮衍生物:<化学式>其中R 1和A表示与上述相同的含义,并且R 3表示由<表示的基团。 CHEM>其中E表示与上述相同的含义; W 1和W 2各自表示羟基或通过彼此结合形成碳-碳键,其可用作式(I)化合物的合成中间体。式(Ⅰ)化合物对禾本科杂草,莎草等具有高除草活性,但对农作物的植物毒性却很低。

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