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Thermoplastic moulding composition based on polycarbonate, two graft copolymers with different graft bases (ASA + AES) and copolymers containing vinyl aromatics and AN

机译:基于聚碳酸酯,两种具有不同接枝基础的接枝共聚物(ASA + AES)以及含有乙烯基芳烃和AN的共聚物的热塑性模塑组合物

摘要

The thermoplastic moulding composition contains, based on components A, B and C, A from 10 to 90 % by weight of at least one polycarbonate, B from 10 to 50 % by weight of at least one graft copolymer, C from 10 to 50 % by weight of at least one thermoplastic copolymer containing at least one vinylaromatic monomer having 8 to 12 carbon atoms and acrylonitrile, and is characterised in that component B comprises B1 from 30 to 70 % by weight, based on B, of a first graft copolymer built up from a1) at least one elastomer (rubber) based on a copolymer, as the graft base, containing at least ethylene and propylene, and a2) a graft shell comprising a21) at least one monoethylenically unsaturated aromatic hydrocarbon having 8 to 12 carbon atoms and a22) at least one ethylenically unsaturated monomer which is copolymerisable therewith, and B2 70 to 30 % by weight, based on B, of a second graft copolymer which has been prepared by emulsion polymerisation and is built up from b1) at least one alkyl acrylate-based elastomer (rubber) having 4 to 12 carbon atoms in the alkyl radical, and b2) a graft shell on this elastomer, comprising b21) at least one monoethylenically unsaturated aromatic hydrocarbon having 8 to 12 carbon atoms and b22) at least one ethylenically unsaturated monomer which is copolymerisable therewith.
机译:基于组分A,B和C,热塑性模塑组合物包含10至90重量%的至少一种聚碳酸酯,B 10至50重量%的至少一种接枝共聚物,C 10至50重量%。至少一种热塑性共聚物,其包含至少一种含有至少一个具有8至12个碳原子的乙烯基芳族单体和丙烯腈的热塑性共聚物,其特征在于,组分B包含基于B为30至70重量%的第一接枝共聚物从a1)至少一种基于共聚物的弹性体(橡胶)作为接枝基础,至少包含乙烯和丙烯,以及a2)接枝壳,其包含a21)至少一种具有8至12个碳原子的单烯键式不饱和芳烃a22)至少一种可与之共聚的烯键式不饱和单体,和B2,基于B,以乳液的方式制备并由b1)构成的第二接枝共聚物,按B的重量计为70%至30%在烷基中具有4至12个碳原子的丙烯酸烷基酯基弹性体(橡胶),以及b2)在该弹性体上的接枝壳,包括b21)至少一种具有8至12个碳原子的单烯键式不饱和芳烃,以及b22)至少可与之共聚的一种烯键式不饱和单体。

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