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Thermotropic adducts from non-mesogenic species bound by hydrogen bonds and method for their preparation

机译:氢键结合的非介晶物种的热致加合物及其制备方法

摘要

Thermotropic adducts corresponding to the general formula: IMAGE in which: SIGMA denotes a group forming at least two hydrogen bonds with the additional functional group denoted by the symbol SIGMA ; A and B denote appropriate substitutions carried by the functional groups SIGMA and SIGMA , which contribute in combination with the structure of the central unit SIGMA - SIGMA to inducing the thermotropic property; p and q = 1 or 2. The central unit SIGMA - SIGMA is derived especially from the complementary pairs: cytosine/isocytosine, guanine/cytosine, adenine/uracil, 2,6-dialkanamidopyridine/uracil and 2,6-dialkanamidopyridine/thymine. The substitutents A and B are, in particular, long aliphatic hydrocarbon chains which may contain one or more heteroatoms, which are branched and have at least 28 atoms.
机译:对应于通式:的热致加合物,其中:SIGMA表示形成至少两个氢键的基团,另外的官能团用符号SIGMA表示; A和B表示由官能团SIGMA和SIGMA携带的适当取代基,它们与中央单元SIGMA-SIGMA的结构结合有助于诱导热致性; p和q = 1或2。中心单元SIGMA-SIGMA特别来自互补对:胞嘧啶/异胞嘧啶,鸟嘌呤/胞嘧啶,腺嘌呤/尿嘧啶,2,6-二烷氨基吡啶/尿嘧啶和2,6-二烷嘧啶吡啶/胸腺嘧啶。取代基A和B特别是长的脂肪族烃链,其可以包含一个或多个杂原子,所述杂原子是分支的并且具有至少28个原子。

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