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A method for preparing a catalyst for aromatization of light hydrocarbons

机译:一种用于轻烃芳构化的催化剂的制备方法

摘要

The present invention concerns a catalyst suited to the aromatization reaction of light hydrocarbons. Such a heterogeneous catalyst contains zinc bound to a zeolite support material. The catalyst in accordance with the invention is prepared by adsorbing the zinc onto the surface of the zeolite support material directly from the vapour phase by way of chemisorption. The zeolite compound acting thus as the support material is here heated to a temperature which is above the condensation temperature of the zinc vapour. Advantageously, the preparation has been carried out at temperatures above 390 °C. The zinc vapour has been brought to contact the zeolite support material, whereby the vapour pressure of zinc is maintained sufficiently high and the duration of its interaction with the support material sufficiently long so as to provide at least an equal amount of or, preferably, an excess of zinc in relation to the available binding sites of the support material. In order to avoid the desorption of absorbed zinc, temperature in the preparation reaction of the catalyst in accordance with the invention has been maintained below 550 °C.
机译:本发明涉及适合于轻烃的芳构化反应的催化剂。这种非均相催化剂包含结合到沸石载体材料上的锌。根据本发明的催化剂通过将锌通过化学吸附直接从气相吸附到沸石载体材料的表面上而制备。在此,将由此用作载体材料的沸石化合物加热到高于锌蒸气的冷凝温度的温度。有利地,所述制备已经在高于390℃的温度下进行。使锌蒸气与沸石载体材料接触,从而使锌的蒸气压保持足够高,并且其与载体材料相互作用的持续时间足够长,从而提供至少等量的或优选地,相对于载体材料的可用结合位点过量的锌。为了避免吸收的锌解吸,已经将根据本发明的催化剂的制备反应中的温度保持在550℃以下。

著录项

  • 公开/公告号EP0438131A1

    专利类型

  • 公开/公告日1991-07-24

    原文格式PDF

  • 申请/专利权人 NESTE OY;

    申请/专利号EP19910100452

  • 申请日1991-01-16

  • 分类号B01J37/02;B01J29/06;C10G35/095;

  • 国家 EP

  • 入库时间 2022-08-22 05:52:41

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