titanium, zirconium and hafnium - enolate as initiators for the polymerization of acrylate monomers to polymers - living.

摘要

Process for preparing "living" polymer, the process comprising contacting one or more acrylic monomers under polymerizing conditions with a polymerization-initiating amount of a tetracoordinate organotitanium, organozirconium or organohafnium enolate polymerization initiator, and "living" polymers produced thereby.