首页> 外国专利> Brief description of the catalytic component on a porous metallic oxide support for the gas-phase polymerization of olefins. Application of the catalyst obtained at the polymerization of olefins

Brief description of the catalytic component on a porous metallic oxide support for the gas-phase polymerization of olefins. Application of the catalyst obtained at the polymerization of olefins

机译:对用于烯烃气相聚合的多孔金属氧化物载体上的催化组分的简要描述。所获得的催化剂在烯烃聚合中的应用

摘要

Treatment process making it possible to maintain the morphology of a catalyst component for the gas-phase polymerisation or copolymerisation of ethylene or of ethylene and of at least one alpha olefin containing from 3 to 12 carbon atoms, the said component containing at least titanium, magnesium, chlorine and optionally an electron-donor, the process consisting, after impregnation of a porous metal oxide support with titanium, magnesium and chlorine compounds and optionally with the electron-donor, in involving this catalyst component in the presence of an alkylaluminium-based cocatalyst in a prepolymerisation, at least partially in suspension, of ethylene or of ethylene and of an alpha-olefin characterised in that the prepolymerisation is conducted, in the presence of a cocatalyst consisting of an alkylaluminium complexed with an electron-donor to a degree of prepolymerisation appropriate to the gas-phase polymerisation process in which the resulting active prepolymer will subsequently be used.
机译:处理过程可以保持用于乙烯或乙烯和至少一种含3至12个碳原子的α-烯烃的气相聚合或共聚的催化剂组分的形态,所述组分至少包含钛,镁,氯和任选的电子给体,该方法包括在用钛,镁和氯化合物以及任选的电子给体浸渍多孔金属氧化物载体之后,在烷基铝基助催化剂存在下使该催化剂组分参与在乙烯或乙烯和α-烯烃的至少部分悬浮的预聚合反应中,其特征在于,在由烷基铝与电子给体络合的助催化剂存在下进行预聚合至一定程度的预聚合适用于气相聚合过程,在该过程中,所得的活性预聚物将随后发生ly被使用。

著录项

  • 公开/公告号FR2616789B1

    专利类型

  • 公开/公告日1991-07-26

    原文格式PDF

  • 申请/专利权人 ATOCHEM;

    申请/专利号FR19870008403

  • 发明设计人 CLAUDE BRUN;AUGUSTE CHEUX;ERIC BARTHEL;

    申请日1987-06-16

  • 分类号C08F10/02;C08F2/34;C08F4/64;

  • 国家 FR

  • 入库时间 2022-08-22 05:48:36

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