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Polyurea and film composed of at least one monomolecular layer of a polyurea

机译:聚脲和由聚脲的至少一个单分子层组成的膜

摘要

A polyurea of the general formula ##STR1## where X and Y are. independently of one another, a divalent radical whose chain contains in each case at least two carbon atoms, and A and B are, independently of one another, H or (C.sub.1 -C.sub.26)alkyl, and n is an integer greater than 4, which polyurea contains at least one (C.sub.6 -C.sub.26) alkyl group per repeating unit, is prepared by reacting the diamine NHA-X-NHB with roughly the equimolar amount of a diisocyanate OCN-Y-NCO. The polyurea is suitable for preparing ordered monomolecular LB films on a base (film-substrate-system). For this purpose it is dissolved in a volatile organic solvent which is not miscible with water, the solution is spread at the water/air interface, and the layer formed is compressed after the solvent has evaporated and it is transferred to a solid layer base by the Langmuir-Blodgett technique.
机译:通式为## STR1 ##的聚脲,其中X和Y为。彼此独立地是一个二价基团,该二价基团的链分别包含至少两个碳原子,并且A和B彼此独立地是H或(C.1 -C.sub.26)烷基,并且n是大于4的整数,其中聚脲每个重复单元包含至少一个(C 6 -C 26)烷基,是通过使二胺NHA-X-NHB与大约等摩尔量的α-氨基反应制备的。二异氰酸酯OCN-Y-NCO。聚脲适合在基底(膜-基底-系统)上制备有序的单分子LB膜。为此,将其溶于与水不溶混的挥发性有机溶剂中,溶液在水/空气界面处扩散,形成的层在溶剂蒸发后被压缩,然后通过Langmuir-Blodgett技术。

著录项

  • 公开/公告号US5081212A

    专利类型

  • 公开/公告日1992-01-14

    原文格式PDF

  • 申请/专利权人 HOECHST AKTIENGESELLSCHAFT;

    申请/专利号US19890414535

  • 发明设计人 WERNER PRASS;UDE SCHEUNEMANN;

    申请日1989-09-29

  • 分类号C08G18/10;

  • 国家 US

  • 入库时间 2022-08-22 05:23:26

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