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PREPARATION OF GLUTACONIC ACID DERIVATIVE
PREPARATION OF GLUTACONIC ACID DERIVATIVE
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机译:葡糖酸衍生物的制备
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A useful intermediate, glutaconic acid ester derivative (III), is prepared by Michael-type condensation of thiazoleacetic acid derivative (I) with alkoxyacrylic acid derivative (II) in the presence of base. IMAGE (I) IMAGE (II) IMAGE (III) (wherein, R is amino or protected amino; R1 is an ester forming group; R2 is hydrogen, cyano, or esterified carboxy; R3 is hydrogen, cyano, or esterified carboxy; and R4 is lower alkyl or aralkyl).
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