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Method prepares macromolecular water-soluble or the expanded polymer that gets into a difficult position

机译:方法制备大分子水溶性或陷入困境的膨胀聚合物

摘要

Aqueous solution of the hydrophilic monomer preparation for 20 to 60% is to be emulsified in grease immiscible phase, usually aliphatic series or clicyclic hydrocarbon. To be emulsified in the monomer solution of 30 to 300 parts by weight in the oily phase of 100 parts by weight. The stable lotion is by 0.The surfactant and HLB of 5 to 50 parts by weight are lower than 8. Polymerization is by being added 0.The peroxide initiator of 1 to 5% weight % such as dibenzoyl peroxide, dilauroyl peroxide, di-tert-butyl peroxide, tert-butyl hydroperoxide, dicumenyl peroxide or diacetyl peroxide, according to the monomer of amount. Polymerization 0. is controlled at a temperature of the decomposition of these initiators is lowThe ferrocene and/or ferrocene monophosphate of 1 to 10% parts by weight are used according to the amount of peroxide initiator. Polymerization reaction carries out under an inert atmosphere, at 25 to 75 degrees Celsius of temperature.
机译:亲水性单体制剂中20%至60%的水溶液要在与油脂不混溶的相中乳化,通常是脂族或脂环族烃。在100重量份的油相中在30至300重量份的单体溶液中乳化。稳定的乳液为0。5至50重量份的表面活性剂和HLB低于8。通过添加0进行聚合。1至5%重量%的过氧化物引发剂,例如过氧化二苯甲酰,过氧化二月桂酰,根据单体的量,过氧化叔丁基,过氧化叔丁基,过氧化二枯烯基或过氧化二乙酰基。聚合0被控制在这些引发剂的分解温度低下。根据过氧化物引发剂的量,使用1至10重量份的二茂铁和/或二磷酸二茂铁。聚合反应在惰性气氛中,在25至75摄氏度的温度下进行。

著录项

  • 公开/公告号CZ664489A3

    专利类型

  • 公开/公告日1993-03-17

    原文格式PDF

  • 申请/专利权人 SYNPO A S;

    申请/专利号CS19890006644

  • 发明设计人 BENDA DUSAN ING;SNUPAREK JAROMIR ING DRSC;

    申请日1989-11-24

  • 分类号C08F20/06;C08F20/56;C08F2/32;C08F2/24;

  • 国家 CZ

  • 入库时间 2022-08-22 05:12:19

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