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LOW VISCOSITY SELF-TOUGHENING ACRYLATE COMPOSITION

机译:低粘度自增韧丙烯酸酯组合物

摘要

LOW VISCOSITY SELF-TOUGHENING ACRYLATE COMPOSITION Compositions comprising: A) A mixture of acrylate functional prepolymers in the total amount of between about 50% and 80% by weight of the composition, said prepolymer mixture comprising a first prepolymer which is a urethane diacrylate resin, suitably a polyether urethane diacrylate, having a viscosity of at least 500,000 cps at 25.degree.C in an amount of between 10 and 40% by weight of the composition, and a second multi-acrylate prepolymer having a viscosity of between about 500 and 50,000 cps in an amount of at least 15% by weight of the composition; B) A monoacrylate diluent monomer selected from the group consisting of isobornyl acrylate, .beta.-carboxyethyl acrylate and mixtures thereof in an amount of at least 5% by weight of the composition; and, C) An effective amount for cure initiation of a free radical initiator, the composition having a viscosity of less than 10,000 cps at 25.degree.C, give unusual selftoughened cured properties. Such compositions, where the free radical initiator is a free radical photoinitiator, are particularly useful in rapid prototyping applications where the requirement for low viscosity and optical clarity of the liquid formulation has heretofore limited use of the formulations to ones giving undesirably brittle or soft properties.
机译:低粘度自增韧丙烯酸酯组合物,包括:A)丙烯酸酯功能预聚物的混合物,其总量占组合物重量的约50%至80%,所述预聚物混合物包含第一预聚物,其为聚氨酯二丙烯酸酯树脂,合适的是聚醚氨基甲酸酯二丙烯酸酯,其在25℃下的粘度为至少500,000 cps,占组合物重量的10%至40%,以及第二种多丙烯酸酯预聚物,其粘度为约500-500cps。 50,000 cps,至少占组合物重量的15%; B)单丙烯酸酯稀释剂单体,其含量为组合物重量的至少5%,选自丙烯酸异冰片酯,丙烯酸β-羧乙酯及其混合物。 C)自由基引发剂固化引发的有效量,该组合物在25℃下的粘度小于10,000cps,产生不寻常的自增韧固化性能。这样的组合物,其中自由基引发剂是自由基光引发剂,特别适用于快速原型应用,其中对液体制剂的低粘度和光学透明性的要求迄今将制剂的使用限制为提供不希望的脆性或软性的那些。

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