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Process for preparing copolymers of ethylene and unsaturated carboxylic acids or unsaturated carboxylic-acid esters or mixtures of these monomers
Process for preparing copolymers of ethylene and unsaturated carboxylic acids or unsaturated carboxylic-acid esters or mixtures of these monomers
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机译:乙烯与不饱和羧酸或不饱和羧酸酯或这些单体的混合物的共聚物的制备方法
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摘要
The copolymers comprise from 96 to 99.6 mol% of ethylene and from 0.4 to 4 mol% of a C3-C6-alkenecarboxylic acid or an ester of this acid having a total of up to 14 carbon atoms, or mixtures of these monomers, and are obtainable by polymerisation in a continuous tubular reactor at a pressure of from 500 to 5000 bar and at elevated temperature in the presence of initiators which decompose to form free radicals, by adding a mixture of said reaction components only at the inlet point of the tubular reactor, the temperature in a first reaction zone being limited to about 240 DEG C, further initiator being metered in at the beginning of a second reaction zone after the temperature has been reduced by from 5 to 20 DEG C, and the reaction being completed at temperatures of up to 300 DEG C.
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