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A method for the production of epoxide - ring opening products with a defined radical - epoxide oxygen content

机译:一种生产具有确定的自由基-环氧化物氧含量的环氧化物-开环产物的方法

摘要

Epoxy compounds can be subject to partial ring opening if they are caused to react in the presence of medium-strong acids from the group formed by phosphoric acid, phosphorous acid and sub-phosphorous acid with nucleophiles and any excessive nucleophiles are then separated without neutralising the catalyst acid. The resultant polyol compounds with a defined residual epoxy oxygen content are valuable raw materials, e.g. for the production of alkyd resins and polyurethane foams.
机译:如果环氧化合物在中等强度的酸(由磷酸,亚磷酸和亚磷酸与亲核试剂形成的组)中反应,则它们会发生部分开环,然后分离出任何过量的亲核试剂而不中和催化剂酸。具有确定的残留环氧氧含量的所得多元醇化合物是有价值的原料,例如用于生产醇酸树脂和聚氨酯泡沫。

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