首页> 外国专利> Presensitised dry lithographic printing plate for scanner - comprises photopolymerisable light sensitive coat contg. tri:aryl methane print=out dyestuff, organic amine and fluorenone cpd. covered by silicone rubber

Presensitised dry lithographic printing plate for scanner - comprises photopolymerisable light sensitive coat contg. tri:aryl methane print=out dyestuff, organic amine and fluorenone cpd. covered by silicone rubber

机译:用于扫描仪的预敏干式平版印刷版-包括可光聚合的光敏涂层。三:芳基甲烷打印=染料,有机胺和芴酮cpd。被硅橡胶覆盖

摘要

The plate has a substrate (I) and a photopolymerisable light-sensitive coat (II) covered by a silicone rubber coat (III). (II) contains a triarylmethane print-out dyestuff (IV), an organic amine (V) and a (substd.) fluorenone (VI). (II) pref. contains 0.01-10 (wt.)% (IV), 0.1-40% (V) and 0.01-30% (VI). It also contains a monomer or oligomer with polymerisable ethylenically unsatd. gp(s)., a photopolymerisation initiator and a film-forming polymeric binder. The plate also has a primer coat between (I) and (II). (III) is obtd. by curing a mixt. of 100 pts. organopolysiloxane with alkenyl gps. attached directly to Si atoms, 0.1-1000 pts. organo-H-polysiloxane with SiH gps. and 0.00001-10 pts. addn. catalyst. USE/ADVANTAGE - Images with high contrast are obtd. and the exposure is practicable (ca. 1/2-2 times the usual exposure). In an example, a primed Al plate was given a 5 g/sq.m (dry) coating with a soln. of 1.5 pts. `Sanprene IB1700D' (RTM), 0.5 pt. `A-1000' (RTM; polyethylene glycol diacrylate), 1.0 pt. adduct of xylylene diamine/glycidyl methacrylate in 1:4 molar ratio, 0.35 pt. ethyl Michler's ketone, 0.10 pt. 2,4-diethylthioxanthone, 0.01 pt. naphthalene sulphonate of Victoria Pure Blue BOH, 0.03 pt. `Defenser MCF 323' (RTM; fluorinated nonionic surfactant, 30% soln. in MIBK), 25 pts. propylene glycol methyl ether and (A) 0.10 pt. fluorenone, (b) no additive, (C) 0.10 pt. anthrone, and samples (B, C) were controls. It was then given a 2 g/sq.m (dry) silicone rubber coat. The plate was exposed through a positive film (20% half-tone dots; density 200 lines/inch) with 30 or 15 counts. The Macbeth density with 0% exposure with standardised light was (A) 0.30, (B) 0.35, (C) 0.40 with 30 counts and (A) 0.30, (B) 0.41, (C) 0.46 with 15 counts; and the half tone dot rating with a plate scanner (A,B,C) 20% with 30 counts and (A) 20, (B, C) 10% with 15 counts. (A) had high print-out properties and was pref. used with a plate scanner
机译:该板具有基材(I)和被​​硅橡胶涂层(III)覆盖的可光聚合的光敏涂层(II)。 (II)包含三芳基甲烷印染染料(IV),有机胺(V)和(基本)芴酮(VI)。 (II)偏好包含0.01-10(wt。)%(IV),0.1-40%(V)和0.01-30%(VI)。它还包含具有可聚合的烯键式不饱和键的单体或低聚物。 gp,光聚合引发剂和成膜聚合物粘合剂。该板还在(I)和(II)之间具有底漆层。 (III)已过时。通过固化混合料。 100分。带有烯基gps的有机聚硅氧烷。直接连接到Si原子上,0.1-1000 pts。具有SiH gps的有机H-聚硅氧烷。和0.00001-10点。地址催化剂。使用/优点-高对比度的图像被遮盖。并且暴露是可行的(大约是通常暴露的1 / 2-2倍)。在一个例子中,涂有底漆的铝板涂有5 g / sq.m(干)的涂层。 1.5分。 Sanprene IB1700D(RTM),0.5点。 A-1000'(RTM;聚乙二醇二丙烯酸酯),1.0磅二甲苯二胺/甲基丙烯酸缩水甘油酯的加合物,摩尔比为1:4,0.35 pt。乙基米氏酮,0.10 pt。 2,4-二乙基噻吨酮,0.01 pt维多利亚纯蓝BOH的萘磺酸盐,0.03 pt。 “防御剂MCF 323”(RTM;氟化非离子表面活性剂,在MIBK中的含量为30%),25分。丙二醇甲醚和(A)0.10 pt。芴酮,(b)无添加剂,(C)0.10点。蒽酮和样品(B,C)作为对照。然后给它涂上2克/平方米(干)的硅橡胶涂层。通过具有30或15计数的正片(20%的半色调网点;密度200线/英寸)曝光该板。在标准光下0%曝光的Macbeth密度为(A)0.30,(B)0.35,(C)0.40(30个计数)和(A)0.30,(B)0.41,(C)0.46(15个计数);平板扫描仪(A,B,C)的半色调点等级为20%,计数为30,(A)为20,(B,C)为10%,计数为15。 (A)具有很高的打印输出性能并且是优选的。与平板扫描仪一起使用

著录项

相似文献

  • 专利
获取专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号