首页> 外国专利> method for rueckgewinnung of entparaffinierungshilfsmittels by asymmetric ultrafiltrationsmembran from polyimid.

method for rueckgewinnung of entparaffinierungshilfsmittels by asymmetric ultrafiltrationsmembran from polyimid.

机译:聚酰亚胺的不对称超滤膜法制备Entparaffinierungshilfsmittels的方法

摘要

Dewaxing aids used to assist in the solvent dewaxing of waxy hydrocarbon oils are recovered from the dewaxed oil or waxy precipitate, or both, by selective permeation of the oil or wax through a perm-selective polyimide ultrafiltration membrane, under ultrafiltration conditions, leaving a retentate of dewaxing aid, of reduced oil and/or wax content, which dewaxing aid-rich retentate can be recycled to the solvent dewaxing process. The polyimide ultrafiltration membranes are preferably produced using a casting solution of polyimide polymer dissolved in a dual solvent system comprising a pro solvent/anti-solvent pair at a ratio of 10:1 to 1:1 and further containing an inorganic salt, said casting solution being used to produce a film which is permitted to evaporate for 1 to 60 seconds and then quenched in a quenching solvent.
机译:在超滤条件下,通过油或蜡通过渗透选择性聚酰亚胺超滤膜的选择性渗透,从脱蜡油或蜡状沉淀物或两者中回收用于帮助蜡状烃油进行溶剂脱蜡的脱蜡助剂。脱蜡助剂,减少的油和/或蜡含量,可将富含脱蜡助剂的滞留物再循环到溶剂脱蜡过程中。所述聚酰亚胺超滤膜优选使用如下的聚酰亚胺聚合物浇铸溶液制备:将其浇铸在双溶剂体系中,所述双溶剂体系包含比例为10:1至1:1的原溶剂/反溶剂对并且还包含无机盐,所述浇铸溶液用这种方法生产的薄膜可以蒸发1至60秒,然后在淬灭溶剂中淬灭。

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