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Composition, concentrate, diesel fuel, methods for operating a diesel engine and a device powered by a diesel engine and process for making a complex containing copper

机译:组合物,浓缩物,柴油,操作柴油发动机的方法和由柴油发动机提供动力的装置以及制备含铜配合物的方法

摘要

This invention relates to copper-containing aromatic Mannich complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing aromatic Mannich complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing aromatic Mannich complex is obtainable by contacting either component (A) or component (B) with component (C); component (A) being at least one compound represented by the general formula CHEM wherein R1 is an alkyl group of 1 to about 6 carbon atoms, and R2 is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; component (B) being a mixture of (B)(I) and (B)(II), component (B)(I) being at least one compound represented by the general formula CHEM wherein R3 is an alkyl group of about 9 to about 18 carbon atoms, R4 is an alkylene group of 1 to about 4 carbon atoms, and R5 is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; and component (B)(II) is at least one compound represented by the formula CHEM wherein R6 and R8 are independently alkyl groups of about 9 to about 18 carbon atoms, and R7 is an alkylene group of 1 to about 4 carbon atoms; and component (C) is at least one copper reactant.d re
机译:本发明涉及含铜的芳族曼尼希配合物,以及涉及含该配合物的精矿和柴油。柴油燃料可用于装有排气系统微粒捕集器的柴油发动机。含铜的芳香曼尼希配合物用于降低收集器中收集的废气颗粒的着火温度。含铜的芳族曼尼希配合物可通过使组分(A)或组分(B)与组分(C)接触而获得。组分(A)为至少一种由通式表示的化合物,其中R 1为1至约6个碳原子的烷基,并且R 2为约16的饱和或不饱和脂族烃基至约20个碳原子;组分(B)是(B)(I)和(B)(II)的混合物,组分(B)(I)是至少一种由通式表示的化合物,其中R 3是烷基大约9至大约18个碳原子的基团,R 4是大约1至大约4个碳原子的亚烷基,并且R 5是大约16至大约20个碳原子的饱和或不饱和脂族烃基;组分(B)(II)是至少一种由式表示的化合物,其中R 6和R 8独立地是约9至约18个碳原子的烷基,并且R 7是1至约4个碳原子的亚烷基;并且组分(C)是至少一种铜反应物。

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