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N, N-disubstituted and N, N, N / N, N, N-trisubstituted thioureas and process for their preparation (II)

机译:N,N-二取代的和N,N,N / N,N,N-三取代的硫脲及其制备方法(II)

摘要

N,N'-disubstituted or N,N,N'- or N,N',N'-trisubstituted thioureas with additional organyloxysilyl function and tertiary amine function of the general formula IMAGE These compounds are prepared as follows: a) Aminoorganylsilanes of the general formula IMAGE are reacted in an organic, inert solvent with carbon disulfide, b) The dithiocarbamates formed thereby having the general formula: IMAGE are isolated and combined with at least the equimolar amount of an amino compound of the general formula H2N-(CH2)n-NR32, this mixture is heated until the reaction is completed and the desired product is subsequently isolated.
机译:具有通式的另外的有机氧基甲硅烷基官能团和叔胺官能团的N,N′-二取代或N,N,N′-或N,N′,N′-三取代的硫脲这些化合物的制备如下:a)氨基有机基硅烷通式的通式(IMAGE)的化合物在有机惰性溶剂中与二硫化碳反应,b)分离出由此形成的通式为的二硫代氨基甲酸酯,并与至少等摩尔量的通式式H 2 N-(CH 2)n -NR 32,加热该混合物直至反应完成,然后分离所需产物。

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