首页> 外国专利> PROCEDURES FOR THE MANUFACTURE AND USE OF BETA-AMINOPROPIC ACIDS, N-DISUBSTITUTED, FOR THE HYDROPHOBITION OF LEATHER AND PELZES.

PROCEDURES FOR THE MANUFACTURE AND USE OF BETA-AMINOPROPIC ACIDS, N-DISUBSTITUTED, FOR THE HYDROPHOBITION OF LEATHER AND PELZES.

机译:N-取代的β-氨基丙酸的制造和使用程序,用于皮革和颗粒的加水。

摘要

A process for the preparation of compounds of the formula I IMAGE in which R1 denotes a saturated or unsaturated alkyl radical or alkoxyalkyl radical having 1 - 22 carbon atoms, preferably 12 - 18 carbon atoms, R2 denotes an alkyl radical having 1 - 18 carbon atoms, a saturated or unsaturated carboxyalkyl radical having 3 - 4 carbon atoms, a carboxyphenyl radical or a carboxyl radical (-COOH), R3 denotes hydrogen or CH3 and X denotes hydrogen, alkali metal, alkaline earth metal, ammonium, alkylammonium or alkanolammonium and A represents 2bLC=O, 2bLSO2, IMAGE or an alkylene radical having 0-3 C atoms, which is characterised in that alkylamines of the formula R1-NH2, in which R1 has the meaning described above, are added to (meth)acrylic acid and the resulting N-alkylaminopropionic acids are reacted with carboxylic anhydrides, carbonyl chlorides, sulphonyl chlorides, isocyanates, halocarboxylic acids or (meth)acrylic acids and are then optionally at least partially neutralised. Novel N-alkyl-N-(2-carboxyethyl)sulphonamides and N-alkyl-N-(2-carboxyethyl)ureas are additionally described.
机译:制备式I 化合物的方法,其中R1表示具有1-22个碳原子,优选12-18个碳原子的饱和或不饱和烷基或烷氧基烷基,R2表示具有1-18个烷基的烷基碳原子,具有3-4个碳原子的饱和或不饱和羧基烷基,羧基苯基或羧基(-COOH),R3表示氢或CH3,X表示氢,碱金属,碱土金属,铵,烷基铵或链烷醇铵A表示<2bL> C = O,<2bL> SO2,或具有0-3个碳原子的亚烷基,其特征在于式R1-NH2的烷基胺,其中R1具有上述含义将其加入(甲基)丙烯酸中,并使所得的N-烷基氨基丙酸与羧酸酐,羰基氯,磺酰氯,异氰酸酯,卤代羧酸或(甲基)丙烯酸反应,然后任选地至少部分中和。 d。另外描述了新型的N-烷基-N-(2-羧乙基)磺酰胺和N-烷基-N-(2-羧乙基)脲。

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