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Optically active amino acid sulfoxide - and sulfone - derivatives, their preparation, their polymerization and use as adsorbents for the chromatographic racemate resolution

机译:光学活性氨基酸亚砜和砜衍生物,其制备,聚合和用作吸附剂的色谱外消旋体分离

摘要

The invention relates to novel optically active amino acid derivatives of the general formula (I) IMAGE in which n, R, R1, R2, R3, X and A have the meaning indicated in the description, which contain sulphoxide or sulphone groups, two fundamental process routes for their preparation from sulphur-containing amino acids, the polymerisation of these monomers and the use of the polymers as optically active adsorbents for the chromatographic resolution of racemates into the enantiomers.
机译:本发明涉及通式(I)的新型光学活性氨基酸衍生物,其中n,R,R1,R2,R3,X和A具有说明书中所指示的含义,其含有亚砜或砜基,由含硫氨基酸制备的两种基本工艺路线,这些单体的聚合以及将聚合物用作旋光色谱法将外消旋物色谱分离成对映体的聚合物。

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