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Binding heavy metal residues in ceramics - by moulding mixt of silt, water and e.g. electroplating sludge then firing

机译:通过模制淤泥,水和其他物质的混合物来粘结陶瓷中的重金属残留物电镀污泥然后烧成

摘要

Prepn. of ceramic bodies, in which heavy metal-contg. residues (HMR) are bound, comprises: forming a mouldable mixt. contg. HMR, water and si moulding a green body from the mixt.; and firing the mixt. to give a dense, sintered, stone- or brick-like body. Alternatively, a mixt. contg. HMR and silt is pressed and fired to give a prod. as above. Ceramic bodies obtd. by the process are also claimed. USE/ADVANTAGE - HMR are esp. hydroxide sludges, specifically from electroplating plants, chemical pptn. or dissolution processes or waste water purificn. plants (all claimed). Such materials are utilised and made harmless in ceramics, from which heavy metals are not, or only very slowly, eluted. Silt contaminated with harmful organic components (e.g. mineral oils or polychlorinated biphenyls) can also be disposed off, as well as other problem materials (added to the ceramic-forming mixt.) such as glass grinding sludges (e.g. as waste from the glass or enamel industry), used casting sand and blasting sand, dust from dry separators (e.g. waste gas purifying filters) and fly ash. The process uses silt, rather than (more expensive) clay. In some cases addn. of flux is unnecessary, since hydroxide sludges can act as flux.
机译:准备陶瓷体,其中含有重金属。残留物(HMR)被结合,包括:形成可模制的混合物。续HMR,水和淤泥;用混合料成型生坯​​。然后开火产生致密的,烧结的,石头或砖状的物体。或者,混音。续将HMR和淤泥压制并发射,以产生产品。如上。陶瓷体。通过该过程也被要求。使用/优势-特别是HMR。氢氧化物污泥,特别是电镀厂的化学污泥。或溶解过程或废水净化。植物(均已声明)。这样的材料在陶瓷中被利用并被制成无害的陶瓷,重金属不会或仅非常缓慢地从中洗脱出来。也可以处理掉被有害有机成分(例如矿物油或多氯联苯)污染的淤泥,以及其他有问题的材料(添加到形成陶瓷的混合物中),例如玻璃研磨污泥(例如来自玻璃或搪瓷的废料)。工业),废砂和喷砂,干式分离器(例如废气净化过滤器)的粉尘和飞灰。该过程使用淤泥,而不是(更昂贵的)粘土。在某些情况下,addn。无需使用助焊剂,因为氢氧化物污泥可以充当助焊剂。

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