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substituted tetrachalkogenfulvalene and procedures in their production.

机译:取代的四链古碱富瓦烯及其生产程序。

摘要

Compounds of the formula I IMAGE (I) in which X1, X2 and X3, independently of one another, are S or Se, R1 and R2, independently of one another, are H, linear or branched C1-C18alkyl-X4- or R1 and R2 together are IMAGE in which X4 is S or Se, z is 0 and n is an integer from 2 to 6 or z is 1 and n is an integer from 1 to 4, R4 and R5, independently of one another, are H or C1-C6alkyl, and R3 is linear or branched C1-C12alkyl or phenyl. The compounds can be converted into unsymmetrically substituted chalcogenofulvalenes, from which electrically conducting charge-transfer complex salts can be prepared.
机译:式I (I)的化合物,其中X 1,X 2和X 3彼此独立地为S或Se,R 1和R 2彼此独立地为H,直链或支链的C 1 -C 18烷基-X 4-或R1和R2一起是,其中X4是S或Se,z是0,n是2到6的整数,或者z是1且n是1-4的整数,R4和R5独立于一个另一个是H或C1-C6烷基,R3是直链或支链C1-C12烷基或苯基。可以将化合物转化为不对称取代的硫属元素富瓦烯,由此可以制备导电的电荷转移复合盐。

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