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Dimensionally stable metallic hydride composition

机译:尺寸稳定的金属氢化物成分

摘要

A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.
机译:稳定的金属氢化物组合物及其制备方法。该组合物包含均呈颗粒形式的金属氢化物,硅藻土和压载金属的均匀混合的混合物。通过对金属氢化物进行一个或多个氢吸收/解吸循环以使氢化物颗粒崩解至小于约100微米的尺寸来制备组合物。颗粒被部分氧化,然后与压载金属和硅藻土混合形成均匀的混合物。将混合物压成小丸并煅烧。优选地,该混合物包括约10体积%。 %或更多的硅藻土和大约50 vol。 %或更多镇流器。可用于该组合物中的金属氢化物包括Zr,Ti,V,Nb,Pd以及La,Al,Cu,Ti,Co,Ni,Fe,Zr,Mg的二元,三元及更复杂的合金, Ca,Mn及其混合物和其他组合。压载金属包括Al,Cu和Ni。

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