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Free radical cured rubber employing acrylate or methacrylate esters of hydroxybenzene and hydroxynaphthalene compounds as co-curing agents

机译:使用羟苯的丙烯酸酯或甲基丙烯酸酯与羟萘化合物作为共固化剂的自由基固化橡胶

摘要

Free radically curable rubbers are crosslinked with the aid of a free radical initiator and a co-curing agent, which is an acrylate or methacrylate ester of a hydroxybenzene or hydroxynaphthalene compound containing two or more hydroxyl groups, at least two of which are esterified. The rubbers which are used in the present invention are natural rubber and synthetic rubbers derived from a diene monomer. Preferred co-curing agents are acrylate and methacrylate esters of hydroxybenzene compounds in which the ester contains two or three acrylate or methacrylate groups per molecule. The amount of co-curing agent may be about 1-50 parts by weight per one hundred parts by weight of rubber (phr). Outstanding abrasion resistance and air oven aging are observed.
机译:自由基可固化橡胶借助于自由基引发剂和共固化剂交联,该共固化剂是含有两个或更多个羟基的羟基苯或羟基萘化合物的丙烯酸酯或甲基丙烯酸酯,其中至少两个羟基被酯化。用于本发明的橡胶是天然橡胶和衍生自二烯单体的合成橡胶。优选的共固化剂是羟基苯化合物的丙烯酸酯和甲基丙烯酸酯,其中该酯每分子包含两个或三个丙烯酸酯或甲基丙烯酸酯基团。每100重量份的橡胶(phr),共固化剂的量可以为约1-50重量份。观察到出色的耐磨性和空气烤箱老化。

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