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YELLOWING-RESISTANT POLY(HEXAMETHYLENE ADIPAMIDE) FIBER

机译:耐黄变性聚己二酰胺纤维

摘要

PURPOSE: To obtain the fiber excellent in the resistance to oxidative yellowing by adding a specific hindered phenolic compound and phosphorous acid to poly(hexamethylene adipamide). ;CONSTITUTION: When poly(hexamethylene adipamide) is polymerized or extruded into fiber, 0.01 to 1wt.% of a hindered phenol selected from the compounds of formula I to III and 0.01 to 1wt.% of a phosphorous acid such as a phosphite ester or organic phoshite salt are added to give poly(hexamethylene adipamide) fibers having remarkability reduced yellowing properties on heating. Especially, the yellowing is reduced in the heat at on post-treatments to give the fiber with high whiteness, thus this polyamide fibers are suitably used in garments. An example of the hindered phenol is 2,4-bis(n-octylthio)-6-(4hydroxy-3,5-di-t- butylanilino)-1,3,5-triazine (formula I), and the phosphotous acid, is for example, tris(2,4-di-t-butylphenyl) phosphite.;COPYRIGHT: (C)1995,JPO
机译:用途:通过向聚(六亚甲基己二酰胺)中添加特定的受阻酚类化合物和亚磷酸,获得具有优异的抗氧化黄变性的纤维。 ;组成:当聚(六亚甲基己二酰胺)聚合或挤出成纤维时,选自式I至III的化合物的受阻酚的量为0.01至1wt。%和亚磷酸酯或亚磷酸酯的亚磷酸的量为0.01至1wt。%。加入有机亚磷酸盐以得到具有显着降低的加热泛黄性能的聚(六亚甲基己二酰胺)纤维。特别是,在后处理时的热量减少了泛黄,从而使纤维具有高白度,因此该聚酰胺纤维适合用于服装。受阻酚的实例是2,4-双(正辛硫基)-6-(4羟基-3,5-二叔丁基苯胺基)-1,3,5-三嗪(式I)和亚磷酸;例如,亚磷酸三(2,4-二叔丁基苯基)酯。;版权所有:(C)1995,日本特许厅

著录项

  • 公开/公告号JPH07118926A

    专利类型

  • 公开/公告日1995-05-09

    原文格式PDF

  • 申请/专利权人 ASAHI CHEM IND CO LTD;

    申请/专利号JP19930266846

  • 发明设计人 TOMIYAMA HIROSHI;SHIMIZU KATSUYA;

    申请日1993-10-26

  • 分类号D01F6/90;C08K5/13;C08L77/06;D01F1/10;D01F6/60;

  • 国家 JP

  • 入库时间 2022-08-22 04:21:30

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