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Aqueous two-component polyurethane coating agent, process for preparing the same and its use in a process for applying a multilayered coating of lacquer

机译:水性双组分聚氨酯涂料,其制备方法及其在施加多层漆中的用途

摘要

PCT No. PCT/EP94/01991 Sec. 371 Date Dec. 20, 1995 Sec. 102(e) Date Dec. 20, 1995 PCT Filed Jun. 18, 1994 PCT Pub. No. WO95/02005 PCT Pub. Date Jan. 19, 1995The present invention relates to an aqueous two-component polyurethane coating composition comprising A) a water-dilutable polyacrylate resin (A) having an OH number of from 40 to 200 mg of KOH/g, an acid number of from 20 to 100 mg of KOH/g and a glass transition temperature of from -40 DEG C. to +60 DEG C., and B) a polyisocyanate component as crosslinking agent, characterized in that the water-dilutable acrylate resin is obtainable by solution polymerization, in the presence of a polymerization initiator, of at least one monomer which is free of carboxyl groups, at least one monomer which contains hydroxyl groups, at least one vinyl ester of alpha -branched monocarboxylic acids having 5 to 18 carbon atoms per molecule and/or at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of alpha -branched monocarboxylic acids having 5 to 18 carbon atoms per molecule, at least one monomer containing carboxyl groups and, if desired, other monomers which are essentially free of carboxyl groups, and after the end of the polymerization the resulting polyacrylate resin is at least partially neutralized and is dispersed in water.
机译:PCT号PCT / EP94 / 01991第二部分371日期1995年12月20日102(e)日期1995年12月20日PCT 1994年6月18日提交PCT Pub。 WO95 / 02005 PCT公布日期为1995年1月19日本发明涉及一种含水两组分聚氨酯涂料组合物,其包含A)OH值为40至200 mg KOH / g,酸值为0.001的水可稀释聚丙烯酸酯树脂(A)。 KOH / g为20至100mg,玻璃化转变温度为-40℃至+ 60℃,以及B)作为交联剂的多异氰酸酯组分,其特征在于所述水稀释性丙烯酸酯树脂可通过溶液获得。在聚合引发剂的存在下,使至少一种不含羧基的单体,至少一种含有羟基的单体,至少一种每分子具有5至18个碳原子的α-支化一元羧酸的乙烯基酯聚合和/或至少一种丙烯酸和/或甲基丙烯酸与每分子具有5至18个碳原子的α-支链一元羧酸的缩水甘油酯的反应产物,至少一种含羧基的单体,如果需要,其他基本上不含羧基的单体,并且在聚合反应结束后,所得聚丙烯酸酯树脂至少部分被中和并分散在水中。

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