首页>
外国专利>
Pallet and potassium, and cadmium, barium or gold-containing coated catalyst, process for its preparation and its use in the production of vinyl acetate
Pallet and potassium, and cadmium, barium or gold-containing coated catalyst, process for its preparation and its use in the production of vinyl acetate
展开▼
机译:托盘和钾以及含镉,钡或金的涂覆催化剂,其制备方法及其在乙酸乙烯酯生产中的用途
展开▼
页面导航
摘要
著录项
相似文献
摘要
The invention relates to Pd/K/Au, Pd/K/Ba and Pd/K/Cd supported catalysts constructed in a shell-shape, their production and their use for the preparation of vinyl acetate from ethylene, acetic acid and oxygen in the gas phase. The said catalysts are produced by impregnating the support particles with a solution of salts of the corresponding elements and then drying them, the dynamic viscosity of the solution being at least 0.003 Pa.s and the solution volume during impregnation being more than 80% of the pore volume of the support particles and the duration of impregnation and the time until the beginning of drying being selected to be short enough so that after drying is completed, a shell of 5% to 80% of the pore volume of the support particles contains the said metal salts.
展开▼
机译:本发明涉及以壳状构造的Pd / K / Au,Pd / K / Ba和Pd / K / Cd负载的催化剂,它们的生产及其在乙烯中由乙烯,乙酸和氧制备乙酸乙烯酯的用途。气相。所述催化剂是通过用相应元素的盐溶液浸渍载体颗粒然后干燥而制得的,溶液的动态粘度至少为0.003Pa·s,浸渍过程中溶液的体积大于催化剂的80%。选择足够短的载体颗粒的孔体积,浸渍时间和直到开始干燥的时间,使得干燥完成后,载体颗粒孔体积的5%至80%的壳中含有所说的金属盐。
展开▼