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Thermoplastic moulding compositions consisting of a copolymer based on alkyl esters of methacrylic acid and a five-step emulsion graft copolymer

机译:热塑性模塑组合物,由基于甲基丙烯酸烷基酯的共聚物和五步乳液接枝共聚物组成

摘要

thermoplastic high, containing essentially $a (a) 20 to 40 wt.% of a copolymerisats, available mainly from $80 to 100 wt.% of at least one c1 - c18 - alkylesters of methacrylic acid and $0 to 20 wt.% of at least one c1 - c18 - alkylesters of acrylic acid, $a and $b (b) 60 b is 80 wt.% of a emulsionspfropfcopolymerisates, built from essentially $a (b1) 2 to 10% by weight.-% of a core, available through polymerization of a monomerengemisches consisting essentially $80 to 99.99 wt.% methyl methacrylate (i), $a 0.01 to 5 wt.% allylmethacrylat (ii) $0 to $19.99% w / w of a monofunktionellen comonomeren (iii) and $(a 0 to 3 wt.% a di - or polyfunk in comonomeren (iv), $a (b2) 15 to 50% by weight.-% of a first shell, a monomerengemisches available by polymerization in the presence of the core (b1) comprising essentially a $60 to 89,99 wt.% of a c1 - c20 - alkylesters of acrylic acid (v) $a 10 to 39.99 wt.% of vinylaromatischen monomers, (vi), 0.01 to 5 wt.% a -% allylmet hacrylat (ii), $a, 0 to 10% by weight.-% methyl methacrylate (i) and / or a monofunktionellen comononeren (iii) and $(a 0 to 3% by weight of a di - or polyfunktionellen comonomeren (iv), $a (b3) 5 to 20 wt.% of a second shell, a monomerengemisches available by polymerization of (b1) said composition the presence of the following stage (b2) obtained polymerisates...
机译:热塑性高聚物,基本上包含$ a(a)20至40 wt。%的共聚酯,主要可从$ 80至100 wt。%的至少一种甲基丙烯酸c1-c18-烷基酯和$ 0至20 wt。%的丙烯酸,a和b(b)中至少一种c1-c18烷基酯(b)60b是乳液的80%(重量),由基本$ a(b1)的2-10%(重量)构成。 ,可通过基本上由$ 80至99.99 wt。%的甲基丙烯酸甲酯(i),$ a 0.01至5 wt。%的烯丙基甲基丙烯酸酯(ii)的单体苯甲酸酯的聚合反应而得到。$ 0至$ 19.99%w / w的单官能酮共聚单体(iii)和(0- 3 wt。%的共聚单体(iv)中的di-或多官能团,$ a(b2)-15%至50%(重量)的第一壳,在核存在下可通过聚合反应获得的单体混合物( b1)基本上包含60-89.99 wt。%的丙烯酸c1-c20-烷基酯(v)$ a 10-39.99 wt。%的乙烯基芳构胺单体,(vi)0.01-5 wt%a- %烯丙基甲基丙烯酸酯(ii),$ a,0 -10%的重量百分比。-%的甲基丙烯酸甲酯(i)和 /或单官能的comononeren(iii)和$(0至3%的重量的di-或多官能的comlenomeren(iv),$ a(b3)5到第二壳的20wt。%,通过(b1)所述组合物的聚合可得到的单体混合物在以下步骤(b2)的存在下得到聚合。

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