首页> 外国专利> Composition of a UV-hardened anti-seizure agent and process for the production of an anti-seizure film.

Composition of a UV-hardened anti-seizure agent and process for the production of an anti-seizure film.

机译:UV硬化的抗咬合剂的组成和用于制备抗咬合膜的方法。

摘要

An ultraviolet curing antifogging agent is disclosed. The composition includes block copolymer (a) having a hydrophilic polymer segment (a1) and a hydrophobic polymer segment (a2). A polar solvent (c) is provided in which the hydrophilic polymer segment (a1) can easily be dissolved while the hydrophobic polymer segment (a2) can not. It further includes a photopolymerizable compound (b), and a photopolymerization initiator (d). The block copolymer (a) contains at least one hydrophilic monomer selected from the group of: a (meth) acrylamide compound represented by the general formula: CH2-CR1CONR2R3; a cyclic (meth)acrylamide compound represented by the general formula CHEM and a hydroxyalkyl (meth)acrylate. Further, the hydrophilic polymer segment (a1) is formed by a radically polymerizable monomer having a functional group such as glycidyl group. The hydrophobic polymer segment (a2) is formed by a radically polymerizable monomer and a hydrophobic monomer which is copolymerizable with the former radically polymerizable monomer. The weight ratio of the hydrophilic polymer segment (a1) to the hydrophobic polymer segment (a2) is 50/50 to 95/5. The photopolymerizable compound (b) can be represented by the general formula CH2=CR1COO(CH2CR4HO)nOCCR1=CH2. The weight ratio of the component (a) to the component (b) is in the range of 10/90 to 90/10 in terms of the solid content. Such compositions have excellent antifogging properties and can be applied to transparent plastic materials to prevent fogging.
机译:公开了一种紫外线固化防雾剂。该组合物包括具有亲水性聚合物链段(a1)和疏水性聚合物链段(a2)的嵌段共聚物(a)。提供一种极性溶剂(c),其中亲水性聚合物链段(a1)可以容易地溶解而疏水性聚合物链段(a2)不能溶解。它还包括光聚合性化合物(b)和光聚合引发剂(d)。嵌段共聚物(a)包含选自由通式CH2-CR1CONR2R3表示的(甲基)丙烯酰胺化合物,和至少一种亲水性单体。通式表示的环状(甲基)丙烯酰胺化合物和(甲基)丙烯酸羟烷基酯。此外,亲水性聚合物链段(a1)由具有缩水甘油基等官能团的自由基聚合性单体形成。疏水性聚合物链段(a2)由可自由基聚合的单体和可与前一种可自由基聚合的单体共聚的疏水性单体形成。亲水性聚合物链段(a1)与疏水性聚合物链段(a2)的重量比为50/50至95/5。光聚合性化合物(b)可以由通式CH 2 = CR 1 COO(CH 2 CR 4 HO)n OCCR 1 = CH 2表示。以固体含量计,组分(a)与组分(b)的重量比在10/90至90/10的范围内。这样的组合物具有优异的防雾性能,并且可以应用于透明塑料材料上以防止起雾。

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