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Conjugated enyne derivative and liquid crystal composition

机译:共轭烯炔衍生物和液晶组成

摘要

A novel, conjugated enyne compound expressed by the following formula (I), which has superior characteristics as an L.C. material and is stable under a usually used environment, and a L.C. composition containing the same are provided: ##STR1## wherein A is 1,4-phenylene or 1,4- cyclohexylene; B, C and D are 1,4-phenylene, 1,4-cyclohexylene, 1,3- dioxane-2,5-diyl, pyridine-2,5-diyl or 1,3-pyrimidine-2,5-diyl; L and M are covalent bond, 1,2-ethylene, oxycarbonyl, carbonyloxy, 1,2-ethenylene, 1,2-ethynylene, oxymethylene or methyleneoxy; n, m and l are 0 or 1; X and Z are H or F; R is fluoroalkyl, alkyl, alkoxy, alkoxyalkyl or alkenyl; Y is alkyl, alkoxy, cyano, halogen, cyanate, alkyl or alkoxy having at least one H replaced by halogen; when n is 0, L is covalent bond; when m or n is 0, M is covalent bond; and m, n and l are not simultaneously 0, PPthe compound having a broad L.C. range, a low viscosity and a suitable &Dgr;n, and being applied to various uses, and reducing the viscosity of L.C. composition containing the same and enlarging the L. C. operation range.
机译:由下式(I)表示的新型共轭烯炔化合物,其具有优异的LC特性。材料,并在通常使用的环境和L.C.下稳定提供了包含它们的组合物:其中A是1,4-亚苯基或1,4-亚环己基; B,C和D是1,4-亚苯基,1,4-亚环己基,1,3-二恶烷-2,5-二基,吡啶-2,5-二基或1,3-嘧啶-2,5-二基; L和M为共价键,1,2-亚乙基,氧羰基,羰氧基,1,2-亚乙炔基,1,2-亚乙炔基,甲醛或亚甲氧基; n,m和l为0或1; X和Z为H或F; R为氟代烷基,烷基,烷氧基,烷氧基烷基或烯基; Y是至少一个被卤素取代的H的烷基,烷氧基,氰基,卤素,氰酸酯,烷基或烷氧基;当n为0时,L为共价键;当m或n为0时,M为共价键; m,n和l不同时为0,具有宽L.C的化合物。范围,低粘度和合适的Δn,并被应用于各种用途,并降低了L.C的粘度。含有相同成分并扩大L.C.操作范围的成分。

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