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Thermoplastic resin film with excellent offset printability and offset prints thereof

机译:具有优异的胶版印刷性的热塑性树脂膜及其胶版印刷

摘要

A thermoplastic resin film having a coated layer thereon, the coating layer comprising a quaternary ammonium salt copolymer comprising (a) a structural unit represented by formula (I): ##STR1## wherein A represents --O-- or --NH--; R.sup.1 represents a hydrogen atom or a methyl group; R. sup.2 represents an alkylene group having from 2 to 4 carbon atoms or -- CH.sub.2 CH(OH)--CH.sub.2 --; R.sup.3, R.sup.4, R.sup. 5, and R.sup.6, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms; R.sup.7 represents an alkyl group having from 1 to 10 carbon atoms or an aralkyl group having from 7 to 10 carbon atoms; n represents an integer of from 1 to 3; and X represents a chlorine atom, a bromine atom or an iodine atom, (b) a structural unit represented by formula (II): ##STR2## wherein R.sup.8 represents a hydrogen atom or a methyl group; and R.sup.9 represents an alkyl group having from 1 to 22 carbon atoms, an aralkyl group having from 7 to 22 carbon atoms or a cycloalkyl group having from 5 to 22 carbon atoms, and (c) a structural unit derived from a monomer copolymerizable with monomers providing structural units (a) and (b) at a (a):(b):(c) weight ratio of 30 to 70:30 to 70:0 to 40. The thermoplastic resin film exhibits excellent offset printability and excellent antistatic properties.
机译:在其上具有涂层的热塑性树脂膜,所述涂层包含季铵盐共聚物,所述季铵盐共聚物包含(a)由式(I)表示的结构单元:其中A表示-O-或-NH -; R 1代表氢原子或甲基; R.sup.2表示具有2-4个碳原子的亚烷基或-CH 2 CH(OH)-CH 2-; R.sup.3,R.sup.4,R.sup。 R 5和R 6可以相同或不同,各自表示具有1-3个碳原子的烷基。 R 7表示具有1至10个碳原子的烷基或具有7至10个碳原子的芳烷基; n表示1至3的整数; X为氯原子,溴原子或碘原子;(b)由式(II)表示的结构单元:其中R 8为氢原子或甲基。 R 9表示碳原子数为1〜22的烷基,碳原子数为7〜22的芳烷基或碳原子数为5〜22的环烷基,(c)衍生自a的结构单元。可与提供结构单元(a)和(b)的单体共聚的单体,其(a):( b):( c)的重量比为30到70:30到70:0到40。热塑性树脂膜表现出出色的胶版印刷性以及出色的抗静电性能。

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