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Coating compositions based on a sterically stabilized nonaqueous dispersion processes for their preparation and their use for the coating of packaging

机译:基于空间稳定的非水分散工艺的涂料组合物的制备及其在包装涂料中的用途

摘要

The invention concerns coating agents based on a sterically stabilized, non-aqueous dispersion which can be prepared by reacting, in an organic solvent in the presence of a dispersion stabilizer, at least one epoxy resin (A) having on average at least 2 epoxy groups per molecule, with at least one diol (B) of the formula HOROH (I), in which R is a group of the formula -Ph-D-Ph- (II), wherein -Ph- is a phenylene group and D is a methylene or propylene group, and optionally with a further component (C), which comprises groups which are reactive to epoxy or hydroxyl groups. The invention is characterized in that: i) the non-aqueous dispersion is prepared in that: 1) in a first step the epoxy resin component (A) is reacted with at least one diol (B) and optionally the component (C) to form a reaction product which contains as end groups phenolic hydroxyl groups and has a phenoxy equivalent weight of at least 246; and 2) subsequently, in step (2), 50 to 100 % of the phenolic hydroxyl groups present in the reaction product obtained in step (1) are reacted with another epoxy resin component (A) and/or component (C); and ii) the coating agent contains at least one phenolic resin.
机译:本发明涉及基于空间稳定的非水分散体的涂料,该涂料可通过在分散稳定剂存在下在有机溶剂中使至少一种平均具有至少两个环氧基的环氧树脂(A)制备每分子具有至少一个式(OH)的二醇(B),其中R是式-Ph-D-Ph-(II)的基团,其中-Ph-是亚苯基,D是亚甲基或亚丙基,以及任选地与另外的组分(C)一起,其包含对环氧基或羟基具有反应性的基团。本发明的特征在于:i)非水分散体的制备方法是:1)在第一步中,环氧树脂组分(A)与至少一种二醇(B)和任选的组分(C)反应,得到形成含有酚羟基作为端基且苯氧基当量重量至少为246的反应产物; 2)随后,在步骤(2)中,使步骤(1)获得的反应产物中存在的50-100%的酚羟基与另一种环氧树脂组分(A)和/或组分(C)反应; ii)涂布剂包含至少一种酚醛树脂。

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