The present invention provides an additive for an additive of a chloride-based zinc-iron alloy electroplating solution and a plating solution containing the same, which can produce a zinc-iron alloy electroplated steel sheet improved in surface roughness, surface color and microstructure of a plating layer I do it repeatedly. The present invention relates to a pharmaceutical composition comprising polyethylene glycol (H (OCH2CH2) NOH is in the range of 10 to 20 and in the range of 20 to 30, and the composition is mixed so that the constituent weight ratio is 1: 2 to 1: 5, and the concentration thereof is 10 to 15 wt% An additive for a chloride-based zinc-iron alloy electroplating solution which is prepared by adding 0.1 to 5.0% by weight and 1.0 to 10.0% by weight of an aromatic acid and a formaldehyde solution to the aqueous polyethylene glycol solution, respectively, based on the weight of the polyethylene glycol, The present invention provides a chloride-based zinc-iron alloy electroplating solution containing 0.5 to 8.0 ml / liter.
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