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Compolymer of styrene and silane coupling agent and synthesizing method thereof and method for improving adhesion performance in fiber reinforced polystyrene composites by using the compolymers

机译:苯乙烯和硅烷偶联剂的共聚物及其合成方法和使用该共聚物改善纤维增强聚苯乙烯复合材料粘合性能的方法

摘要

Novel agents for improving adhesion performance between fibers and resins in fiber reinforced polystyrene composites and synthesizing method thereof and method for improving adhesion performance in fiber reinforced polystyrene composites by using the copolymers are disclosed. P PThe agents are copolymers of styrene and silane coupling agents, and the copolymers can be manufactured by copolymerizing styrene monomer and silane coupling agents in benzene solvent at nitrogen atmosphere by employing azobisisobutyronitrile (AIBN) and the like as an initiator after purifying the reactants and eliminating polymerization inhibitor from the reactants.PPThe typical copolymer is poly(styrene-co--MPS)(-MPS means - methacryloxypropyltrimethoxysilane) which is manufactured by copolymerizing styrene monomer and -MPS.PPAdhesion performance of the polystyrene fiber composites is improved by hydrolyzing the copolymer in the presence of solvent and applying the copolymer to the surface of the fibers for reinforcing and then immersing the fibers into polystyrene resin composition after drying.P PFiberglass materials are most preferably employed as fibers for reinforcing.PPAdhesion performance between the fibers and matrix resin is substantially improved, resulting in enhanced the strength and endurance of the composite.
机译:公开了用于改善纤维增强的聚苯乙烯复合材料中的纤维与树脂之间的粘合性能的新型试剂及其合成方法,以及通过使用所述共聚物来改善纤维增强的聚苯乙烯复合材料中的粘合性能的方法。

所述试剂是苯乙烯和硅烷偶联剂的共聚物,并且可以通过在氮气氛下通过使用偶氮二异丁腈(AIBN)等作为引发剂在苯溶剂中使苯乙烯单体和硅烷偶联剂在苯溶剂中共聚来制备共聚物。

典型的共聚物是聚(苯乙烯-co-MPS)(-MPS是指-甲基丙烯酰氧基丙基三甲氧基硅烷),它是通过使苯乙烯单体与-MPS共聚而制得的。通过在溶剂存在下水解共聚物并将共聚物施涂到纤维表面以增强强度,然后在干燥后将纤维浸入聚苯乙烯树脂组合物中,从而改善了聚苯乙烯纤维复合材料的粘合性能。 P>玻璃纤维材料最优选用作增强纤维。

纤维与基体树脂之间的粘合性能大大提高,从而增强了复合材料的强度和耐久性。

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