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LIQUID CRYSTAL COMPOUND BEARING BRANCHED ALKYL GROUP IN SIDE CHAIN AND LIQUID CRYSTAL COMPOSITION CONTAINING THE COMPOSITION
LIQUID CRYSTAL COMPOUND BEARING BRANCHED ALKYL GROUP IN SIDE CHAIN AND LIQUID CRYSTAL COMPOSITION CONTAINING THE COMPOSITION
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机译:侧链中带有支链烷基的液晶化合物和包含该成分的液晶组成
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摘要
PROBLEM TO BE SOLVED: To obtain a new liquid crystal compound excellent in compatibility, compatibility with other liquid crystal compounds esp. at a low-temperature, having a large positive dielectric constant anisotropy and an extremely low viscosity and also an extremely high resistivity and a good UV stability. ;SOLUTION: This liquid crystal compound is expressed by formula I (R1 is a 3-10C branched alkyl; ring A is 1,4-phenylene or 1,4-cyclohexylene; Z1 and Z2 are each a single bond or 1,2-ethylene; X1-X4 are each F or H; Y1 is 0 or a single bond), e.g. 4-{4-[-(4-methylpentyl)cyclohexyl]cyclohexyl}-1- trifluoromethoxybenzene. The compound of formula I, for example, a compound of formula II as one kind of the compound of formula I, is obtained by making a Grignard reagent act on a cyclohexane derivative of formula III to produce an alcohol from of formula IV, which is then treated with an acid into a cyclohexene derivative of formula V, which is, in turn, hydrogenated in the presence of a catalyst. The other objective liquid crystal composition using the compound of formula I has characteristics suitable for application to TFT system.;COPYRIGHT: (C)1997,JPO
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机译:解决的问题:为了获得相容性,与其他液晶化合物特别是相容性优异的新型液晶化合物。在低温下具有大的正介电常数各向异性和极低的粘度,以及极高的电阻率和良好的紫外线稳定性。 ;解决方案:该液晶化合物由式I表示(R 1 Sub>是3-10C的支链烷基;环A是1,4-亚苯基或1,4-亚环己基; Z 1 Sub>和Z 2 Sub>均为单键或1,2-亚乙基; X 1 Sub> -X 4 Sub>分别为F或H ; Y 1 Sub>为0或单键),例如4- {4-[-(4-甲基戊基)环己基]环己基} -1-三氟甲氧基苯。式I化合物,例如作为式I化合物的一种的式II化合物,是通过使格氏试剂作用于式III的环己烷衍生物以从式IV制备醇而获得的。然后用酸处理成式Ⅴ的环己烯衍生物,然后在催化剂存在下将其氢化。使用式I化合物的另一种目标液晶组合物具有适合应用于TFT系统的特性。;版权所有:(C)1997,JPO
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